Influence of second sphere hydrogen bonding interaction on a manganese(II)-aquo complex.
نویسندگان
چکیده
We have developed a pentadentate N(4)O ligand scaffold with a benzimidazole group placed in a rigid fashion to develop hydrogen bonding interaction with the ligand in the sixth position. The mononuclear Mn(II) complex with a water molecule was isolated and characterized. We discuss the role of the outer sphere ligand in stabilising a Mn(II)-aquo complex.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 41 6 شماره
صفحات -
تاریخ انتشار 2012